By J R Ruaya
When the wind dies down or the sun stops shining at night or during cloudy days, the solar collectors and wind turbines stop working. There is just no cost effective way of storing energy from these sources.
Not anymore.
A recent development of energy storage using vanadium electrochemical cells is now about to break into the commercial realm.
In a solar installation photovoltaic solar panels catch the sun’s energy and convert it into electricity. This is then stored into the vanadium battery so that the energy can be used at a later time or pumped into the grid.
A vanadium battery, which works similarly as the familiar battery used in toys and flashlights, has distinct advantages over the other battery cells in the target application. The main advantage is it uses the same elements in both half-cells which eliminates cross-contamination of the two half-cell electrolytes during prolonged use. The positive and the negative half-cells are separated by a proton exchange membrane.
It has high efficiencies of 80 – 90 % in large installations. Furthermore, the costs rapidly goes down as the installation is scaled up. And maintenance is easy.
The battery can also be fully charged or discharged. In cases where time is the essence, the electrolyte solutions can simply be replaced rather than waiting for recharging.
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Sidebar:The electrochemistry involved is not too difficult to understand even by undergraduate students of chemistry. The schematic is shown below (courtesy of the University of New South Wales):

The half-reactions are:
At the positive electrode:
VO2+ + 2H+ + e = VO2+ + H2O E° = 1.00V
At the negative electrode:
V3+ + e- = V2+ E° = -0.26 V
The standard cell potential E° (cell) is 1.26 Volts at concentrations of 1 mole per litre and at 25°C, but under actual cell conditions, the open circuit cell voltage is 1.4 Volts at 50% state-of-charge and 1.6 Volts at 100% SOC (Skyllas-Kazacos, 2002, p. 2).
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Early demonstration projects include a solar-powered housed in Thailand, an electric golf cart, and a back-up power system for a nuclear submarine.
In the United States, which is playing catch up with the technology, a 15-kW photovoltaic installation has just been put up at the Lowry Park Zoo in Tampa, Florida jointly by Tampa Electric and the University of South Florida’s (USF) Power Center for Utility Explorations (PCUE) at a cost of approximately $ 575,000 (Tampa Electric, 2008).
Earlier in June, two similar 5 kWx4hr systems have been installed at the downtown St. Peteresburg campus of USF and at Albert Whitted Park in the same city by the university and Progress Energy of Florida (VRB, 2008).
The vanadium redox battery has been developed and its use pioneered at the University of New South Wales. An engaging historical and scientific account of its development has been presented by Skyllas-Kazacos (2002).
With the technology now available what remains is the development of policy initiatives as embodied in the renewable energy bill still pending in Congress for the solar and wind power to take off in the Philippines.
References
Skyllas-Kazacos, M. (2002, July). An historical overview of the vanadium redox flow battery development at the University of New South Wales, Australia, 13. Retrieved August 19, 2008, from http://www.vrb.unsw.edu.au/overview.htm
Tampa Electric (2008, August 4 news release). Tampa Electric, USF partner with Tampa’s Lowry Park Zoo to develop new renewable energy project. Retrieved August 19, 2008 from http://www.tampaelectric.com/news/article/index.cfm?article=466.
VRB Power Systems Inc. (2008, June 9 press release). Progress Energy and University of South Florida’s Power Center for Utility Explorations unveil two 5kW x 4hr VRB Energy Storage Systems as part of SEEDS project . Retrieved August 19, 2008 from http://www.vrbpower.com/docs/news/2008/news_20080609.pdf